| 577 | 16 | 19 |
| 下载次数 | 被引频次 | 阅读次数 |
聚合物微胶囊是一类新型高分子功能材料,在医药科学、生物化学和材料科学等诸多领域具有广阔的应用前景。本文介绍了一种新颖、灵活的制备微胶囊方法:层层自组装技术(LbL)。同时对各物理特性及其应用进行了综述。
Abstract:Polymer microcapsule is a kind of new functional polymer materials,has a broad application prospect in medical science,biochemistry and materials science,and many other fields.The article focuses on a novel and versatile technique of layer-by-layer(LbL) deposition,meanwhile,The physical properties of self-assembled microcapsule and its application are reviewed.
[1]梁治齐.微胶囊技术及其应用[M].北京:中国轻工业出版社,1999:1~3
[2]Brannonpeppas L.Acs Symposium Series[J].1993,520:42~52
[3]Jung J,Perrut M.Journal of Supercritical Fluids[J].2001,20:179~219
[4]梁振鹏,王朝阳,孙启龙.化学进展[J].2004,16:485~491
[5]高长有,沈家骢.自然科学进展[J].2004,14:495~500
[6]Sukhorukov G.B,RogachA.L,Garstka M,et al.Small[J].2007,3:944~955
[7]IIer R K.Multilayers of colloidal particles[J].J Colloid Interf.Sci,1966,21(6):569~594
[8]Keller S W,Johnsons A,et al.Photoinduced charge separation inmultilayer thin films grown by sequential adsorption of polyelectro-lytes[J].J Am Chem Soc,1995,117(6):12879~12880
[9]Decher G.Fuzzy nano assemblies:Toward layered polymeric Multi-composites[J].Science,1997,277(24):1232~1237
[10]Zhang Y W,Jiang M,Zhao J X,et al.A novel route to thermosen-sitive polymeric core-shell aggregates and hollow spheres in aque-ous media[J].Adv.Funct Mater,2005,15(4):695~699
[11]Xie D,Jiang M,Zhang Z,et al.Hydrogen-Bonded dendronizedpolymers and their self-assembly in solution[J].Chem Eur J,2007,13(12):3346~3353
[12]Glinel K,Moussa A,Jonas A,et al.Influence of PolyelectrolyteHHJ Charge Density on the Formation of Multilayers of StrongPolyelectrolyres At Low Ionic Strength[J].Langmuir 2002,18:1408~1412
[13]Leporatti S,et al.Scanning force microscopy investigation of poly-electrolyte nano-and microcapsule wall texturelangmuir[J].EurPhys J E,2000,16:4058~4059
[14]Sukhishvili S A,Granick S.layered erasable polymer multilayersformed by hydrogen-bonded sequential self-assembly[J].Macro-molecules,2002,35:301~310
[15]Zeng G H,Gao J,Chen S.L,et al.Combining Hydrogen-BondingComplexation in Solution and Hydrogen Bonding-Directed Layer-by-Layer Assembly for the Controlled Loading of a Small Organic Mole-cule into Multilayer Films[J].Langmuir,2007,23:11631~11636
[16]Wang Z Q,Zhang X,Shen J C,et al.Investigation of the covalent-ly attached multilayer architecture based on diazo-resins and poly(4-Styrene sulfonate)[J].Macromol Chem Phys,2001,202(7):967~973
[17]Kim B S,Park S W,Hammond P T.Hydrogen-bonding layer-by-layer assembled biodegradable polymeric micelles as drug deliveryvehicles from surfaces[J].ACS Nano,2008,2(2):386~392
[18]Anzai J,Kobayashi Y,Hoshi T,et al.Construction of MultilayerThin Films of Enzymes by Means of Sugar-Lectin Interactions,Langmuir[J].2000,16:2851~2856
[19]Sukhishvili S.A,Granick S.layered erasable ultrathin polymerfilms[J].J.Am.Chem.Soc,2000,122:9550~9551
[20]Gao C Y,Moya S,Donath E,Mohwald H.Melamine formaldehydecore decomposition as the key step controlling capsule integrity:Optimizing the polyelectrolyte capsule fabrication[J].Macromo-lecular Chemistry and Physics,2002,203(7):953~960
[21]Gao C,Donath E,Moya S,et al.Elasticity of hollow polyelectro-lyte capsules prepared by the layer-by-layer technique[J].Eur.phys.J.E.2001,5:21~27
[22]Vinogradova OI,Lebedeva OV,Kim BS.Mechanical behavior andcharacterization of microcapsules[J].Ann.Rev.Mater.Res.2006,36:143~178
[23]Shiratori S S,et al.pH-Dependent thickness behavior of sequen-tially adsorbed layers of weak polyelectrolytes[J].Macromole-cules,2000,33:4213
[24]Ibarz G,et al.Smart micro-and nanocontainers for storage,trans-port,and release[J].Adv Master,2001,13(17):1324
[25]Lvov Y,Antipov A A,Mamedov A.Urease Encapsulation in nano-organized microshells[J].Nano Letters.2001,l(3):125~128
[26]Gao C Y,et al.Swelling and shrinking of polyelectrolyte micro-capsules in response to changes in temperature and ionic strength[J].Chem Eur J,2003,9:915
[27]Leporatti S,et al.Shrinking of ultrathin polyelectrolyte multilayercapsules upon annealing:A confocall laser scanning microscopyand scanning force microscopy study[J].Eur Phys J E,2001,5:13
[28]Gao C Y,et al.Enhanced biomacromolecule encapsulation byswelling and shrinking procedures[J].Chem Phys Chem,2004,5(1):116
[29]Gao C Y,et al.Spontaneous deposition of horseradish peroxidaseinto polyelectrolyte multilayer capsules to improve its activity andstability[J].Chem Comm,2002(17):1928
[30]孟宪伟,程丛,董振强,等.聚合物空心微球的研究进展[J].高分子通报,2011,3(3):57~63
[31]任科峰,计剑,沈家骢.层-层自组装构建固相可降解基因传递体系的研究[J].高等学校化学学报,2004,25(8):1576~1578
[32]Cheng C J,Chu L Y,Ren P W,et al.Preparation of monodispersethermo-sensitive poly(N-isopropylacry-lamide)hollow microcap-sules[J].J Colloid Interface Sci,2007,313(4):382~388
[33]Ha W,Meng X W,Li Q,et al.studies and selective membranepermeability properties of self-assembly hollow nanospheres[J].Soft matter,2011,06:1018~1014
[34]Tiourina O P,Radtchenko I,Sukhorukov G B,et al.Artificial CellBased on Lipid Hollow Polyelectrolyte Microcapsules:ChannelReconstruction and Membrane Potential Measurement[J].J MembraneBiol,2002,190(1):9~16
[35]Rabiei A,O'Neill A.A study on processing of a composite metalfoam via casting[J].Mater Sci Eng:A,2005,404(1-2):159~164
[36]Midha S,Hofrichter B D,Thomson S R.Shampoo containing hol-low particles[P].US 20030086896.2003~05~08
[37]王东伟.中空结构聚合物微球的制备及其性能研究[D].山东大学,2008
[38]赵庆美.中空聚合物微球的制备及性能研究[D].武汉理工大学,武汉,2008
基本信息:
中图分类号:R944
引用信息:
[1]孙丽,苗明,吕顺忠,等.层层自组装聚合物微胶囊的发展与应用[J].农垦医学,2013,35(02):145-149.
基金信息:
乌鲁木齐市科学技术计划项目(Y08231006)
2013-04-15
2013-04-15